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Formation of Ga2O3 and NiO Thin Films at Low Process Temperatures for PN Heterojunction Diodes
Journal
ACS Applied Electronic Materials
Vol
7
Page
3402-3408
Author
Heejoong Ryou, Sunjae Kim, Dongbin Kim, Jongsu Baek, Yu-Jin Song, Jung Han Kim, Byung Jin Cho, Hyoung Woo Kim, and Wan Sik Hwang
Year
2025
Date
April 3, 2025

Abstract 

 A heterojunction consisting of n-type Ga2O3 and p-type NiO thin films is fabricated at low process temperatures. This technology offers the potential to improve heterojunction applications with wide bandgap semiconductors on various substrates. Optical bandgap values of 4.67 and 3.62 eV are obtained for the Ga2O3 and NiO semiconductors, respectively, from a Tauc plot. The spontaneously formed depletion region in the heterojunction has capacitive characteristics under thermal equilibrium conditions, while the resistive component is involved in the charge transport under the turn-on voltage ranges. The maximum electric field at the heterojunction interface with 50 nm thick n-Ga2O3 is five times higher than that of the n-Ga2O3 with a thickness of over 400 nm under thermal equilibrium conditions. When the junction thickness becomes shorter than the junction depletion width, the diode suffers from an early breakdown due to the much higher maximum electric field at the PN junction interface.